ISSN 2410-7751 (Print)
ISSN 2410-776X (Online)
Ж-л "Biotechnologia Acta" Т. 13, № 6 , 2020
Р. 13-23, Bibliography 34, English
Universal Decimal Classification: 628.161
https://doi.org/10.15407/biotech13.06.013
Institute of Engineering Thermophysics of the National Academy of Sciences of Ukraine, Kyiv
The use of plant biomass as a primary source of energy is currently unacceptable both from an economic and environmental point of view. The experience of a number of industries, in particular hydrolysis production, enables to solve the problem of profitability of organic biomass treatment by its deep complex processing with the resulting components whose cost exceeds the cost of organic raw materials as fuel. Currently, the main results of complex processing of organic raw materials are still energy-intensive products — bioethanol and hydrolyzed lignin, which energy characteristics are commensurate with fossil fuels. Bioethanol production from starch-containing, sugar-containing or lignocellulosic raw materials requires the use of different technological stages and, accordingly, the cost of bioethanol for each type of raw material is different. Compared to bioethanol produced from sugar and starch raw materials, bioethanol manufactured from lignocellulosic raw materials is more expensive. Bioethanol obtained from lignocellulosic raw materials is more expensive compared to bioethanol from sugar and starch raw materials. The most energy-intensive in the technology of bioethanol obtaining from lignocellulosic raw materials is the stage of pretreatment of raw materials for hydrolysis, because the process of preliminary preparation and hydrolysis with dilute acids occurs at high temperatures and pressures. During enzymatic hydrolysis, the process temperature is maintained for a long time (up to several days). To ensure deep integrated processing of plant raw materials, as well as to reduce overall costs, it was proposed to improve the technology and equipment, which allow increasing the degree of conversion of raw materials into basic and by-products.
Ключевые слова: bioethanol, biomass, preliminary preparation, hydrolysis, lignin, rotary pulsation apparatus.
© Palladin Institute of Biochemistry of National Academy of Sciences of Ukraine, 2020
References
1. Wikipedia website. Biomass Available at: https://ru.wikipedia.org/wiki/%D0%91%D0%B8%D0%BE%D0%BC%D0%B0%D1%81%D1%81%D0%B0
2. Himach N. Ju., Polunkin E. V., Glikina I. M., Shelud'ko E. V., Kremeneckij V. V., Shershnev S. A. Advantages of using methods of dispersion and mechanochemical activation of the catalyst to obtain synthetic motor fuels from synthesis gas. Sovremennaja nauka. 2012, 1 (9), 73?79 (In Russian).
3. A practical guide to the use of biomass as a fuel in the municipal sector of Ukraine. URL: http://dia.dp.gov.ua/wp-content/uploads/2019/04
4. Yinon M. Bar-On, Rob Phillips, Ron Milo. The biomass distribution on Earth. PNAS. 2018, 115 (25), 6506?6511. https://doi.org/10.1073/pnas.1711842115
5. Tihonravov V. S., Fedorenko V. F., Buklagin D. S., Mishurov N. P. Deep processing of biomass and agricultural waste. Moskva :Rosinformagroteh. 2014, 256 p. (In Russian).
6. Biofuels are the future of Ukraine's sugar industry. Available at: http://www.ukrsugar.com/uk/post/biopalivo-majbutne-cukrovoi-galuzi-ukraini
7. Hossain Zabed, Golam Faruq, Jaya Narayan Sahu, Mohd Sofian Azirun, Rosli Hashim, Amru Nasrulhaq Boyce. Bioethanol Production from Fermentable Sugar Juice. The Scientific World J. 2014, P. 1?11. https://doi.org/10.1155/2014/957102
8. Pryshliak V. M., Pryshliak N. V. Technical, economic and environmental aspects of bioethanol production in Ukraine. Naukovi pratsi Instytutu bioenerhetychnykh kultur i tsukrovykh buriakiv: Zb. nauk. prats. In-t bioenerhet. kultur i tsukr. buriakiv of Nats. akad. ahrar. Nauk Ukrainy. Kyiv: FOP Korzun D. Iu. 2013, Issue 19, P. 219?226. (In Ukrainian).
9. An EPC Company ZAVKOM website. Available at: http://zavkomgroup.com/ru/division/biotechnologies/deep-processing-grains
10. Pryshliak N. V. Efficiency of biofuel production at the enterprises of the beet-sugarcomplex. Ph .D. dissertation, Faculty of Economics and Entrepreneurship. Vinnytskyi natsionalnyi ahrarnyi universytet. Vinnytsia, Ukraine. 2015.
11. Lotysh A. By-products of sugar production or how to make money on alternative products. Tsukor Ukrainy. 2015, 1 (109), 31?33. (In Ukrainian). http://ukrsugar.com/uk/post/cukor-ukraini-no1-109
12. Kaletnik H. M., Skoruk O. P., Branytskyi Yu. Iu. Organizational and economic principles of organization of biofuel production in Vinnytsia region on the basis of Uladovo-Lyulinetska DSS. Ekonomika. Finansy. Menedzhment: aktualni pytannia nauky i praktyky. 2017, N 5, P. 7?25. (In Ukrainian). http://nbuv.gov.ua/UJRN/efmapnp_2017_5_3
13. Oliinichuk S. T., Sosnytskyi V. V. Advanced technologies of biofuels from plant raw materials. Prodovolchi resursy. 2014, N 2, P. 8?14. (In Ukrainian). http://nbuv.gov.ua/UJRN/pr_2014_2_4
14. Sait Derzhavnoi sluzhby statystyky. Realizatsiia promyslovoi produktsii za vydamy za perelikom PRODCOM. (In Ukrainian). URL: http://www.ukrstat.gov.ua
15. Nahurskyi O. A., Malovanyi M. S., Bunko V. Ia. Application of beet-sugar production waste for production of ecologically safe encapsulated mineral fertilizers. TsukorUkrainy. 2014, N 5, P. 39?41. (In Ukrainian). http://nbuv.gov.ua/UJRN/Cu_2014_5_8
16. Kaletnik H. M., Oliinichuk S. T., Skoruk O. P. Economic efficiency of bioethanol production and use in Ukraine. Zbirnyk naukovykh prats VNAU. Seriia: Ekonomichni nauky. 2012, 1 (56), 3?6. (InUkrainian). http://econjournal.vsau.org/files/pdfa/491.pdf
17. Tutt M., Kikas T., Olt J. Influence of different pretreatment methods on bioethanol production from wheat straw. Agronomy Res. Biosystem Engineering. 2012, Special Issue 1, P. 269?276. https://agronomy.emu.ee/vol10Spec1/p10s131.pdf
18. “Vogelbusch Biocommodizes GmbH” website. Available at: https://www.vogelbusch-biocommodities.com/technology-ru/alcoholru/bioethanol-ru/#FAQ
19. “Vogelbusch Biocommodizes GmbH” website. Available at: https://www.vogelbusch-biocommodities.com/ru
20. Cheng M. H., Huang H., Dien B. S., Singh V. The costs of sugar production from different feedstocks and processing technologies. Biofuels Bioprod. Biorefining. 2019, V. 13, P. 723–739. https://doi.org/10.1002/bbb.1976
21. Sassner Per, Galbe Mats, Zacchi Guido. Techno-economic evaluation of bioethanol production from three different lignocellulosic materials. Biomass and Bioenergy. 2008, V. 32, P. 422?430. https://doi.org/10.1016/j.biombioe.2007.10.014
22. Cheng M. H., Huang H., Dien B. S., Singh V. The costs of sugar production from different feedstocks and processing technologies. Biofuels Bioprod. Biorefining. 2019, V. 13, P. 723–739. https://doi.org/10.1002/bbb.1976
23. Halchynska Yu. M. Assessment of the biomass potential of crop by-products in the agricultural sector of the economy. Ekonomika APK. 2019, N 5, P. 15?26. http://nbuv.gov.ua/UJRN/E_apk_2019_5_5 https://doi.org/10.32317/2221-1055.201905015
24. Valdivia M., Galan J. L., Laffarga J., Ramos J. L. Biofuels 2020: Biorefineries based on lignocellulosic materials. Microb. Biotechnol. 2016, 9 (5), 585?594. https://doi.org/10.1111/1751-7915.12387
25. Micro- and nanoscale processes in DPIE technologies: Thematic collection of articles edited by А. А. Dolinskii. Institute of Engineering Thermophysics. Kyiv: Akademperyodyka. 2015, 464 p. (In Russian).
26. Obodovich O. M., Grabova T. L., Koba A. R., Gorjachev O. A. Improvement of the technology of wort preparation from starch-containing raw materials in alcohol production using the method of discrete-pulse energy input. Promyshlennaya teplotehnika. 2007, 29 (4), 59-63. (In Russian).
27. Lymar A. Iu. Features of discrete-pulse energy input during dispersion of starch-containing raw materials. Ph. D. dissertation. Institute of Engineering Thermofysika. Kyiv, Ukraine. 2014. (In Ukrainian).
28. Sablii L. A., Obodovych O. M., Sydorenko V. V., Sheyko T. V. Study of wheat straw delignification in a rotary-pulsation apparatus. Acta Periodica Technologica. 2020, N 51, P. 103-111. https://doi.org/10.2298/APT2051103S
29. Ukrainian viewon "bioethanol": history, projects, prospects. Available at: http://www.ukrsugar.com/uk/post/ukrainskij-poglad-na-bioetanol-istoria-proekti-perspektivi (in Ukrainian).
30. Ayesha Naseer, Anum Jamshaid, Almas Hamid, Nawshad Muhammad, Moinuddin Ghauri, Jibran Iqbal, Sikander Rafiq, Shahzad Khuram, Noor Samad Shah. Lignin and Lignin Based Materials for the Removal of Heavy Metals from Waste Water-An Overview. Z. Phys. Chem. 2019, 233 (3), 315–345. https://doi.org/10.1515/zpch-2018-1209
31. Suteu D., Zaharia C., Malutan T. Biosorbents based on lignin used in biosorption processes from wastewater treatment. A review. Lignin: Properties and Applications in Biotechnology and Bioenergy. Ryan J. Paterson (Ed.) Nova Science Publishers Inc. 2012, P. 278?305. https://www.academia.edu/31163115/Biosorbents_based_on_lignin_used_in_biosorption_processes_from_wastewater_treatment_A_review
32. Asina F., Brzonova I., Kozliak E., Kubatova A., Ji Y. Microbial treatment of industrial lignin: Successes, problems and challenges. Renew. Sustain. Energy Rev. 2017, V. 77, P. 1179–1205. https://doi.org/10.1016/j.rser.2017.03.098
33. Yu O., Kim K. H. Lignin to Materials: A Focused Review on Recent Novel Lignin Applications. Appl. Sci. 2020, 10 (13), 4626. https://doi.org/10.3390/app10134626
34. Koutinas A. A., Yianoulis P., Gravalos K., Koliopoulos K. A processing scheme for industrial ethanol production from straw. Energy Conv. Management. 1981, 21 (2), 131?135. https://doi.org/10.1016/0196-8904(81)90034-0